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Studies on Rhodium-Catalyzed (5+2) Cocyclization Rections

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Studies on Rhodium-Catalyzed (5+2) Cocyclization Rections (Tienda española)

Hermann Wegner (Autor)

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The first part of this thesis dealt with the a new kind of precursors for transition metalcatalyzed cocyclization reactions containing a vinylbicyclopropyl unit, their synthesis and their behavior in cocyclization reactions. By introducing a second cyclopropane the catalyst might open this ring as well after insertion into the first cyclopropane ring. The ’basic’ formal [5+2] cycloaddition reaction would be extended to a [5+2+3] cocyclization reaction to form ten-membered rings. In addition to the importance as a new synthetic tool valuable insights into the mechanism of transition metal-catalyzed cocyclization reactions of vinylcyclopropanes are gained.

ISBN-10 (Impresion) 3865372090
ISBN-13 (Impresion) 9783865372093
ISBN-13 (E-Book) 9783736912090
Idioma Deutsch
Numero de paginas 140
Laminacion de la cubierta mate
Con folder Si
Edicion 1 Aufl.
Volumen 0
Lugar de publicacion Göttingen
Lugar de la disertacion Göttingen
Fecha de publicacion 20.09.2004
Clasificacion simple Tesis doctoral
Area Química