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Editorial Cuvillier

Publicaciones, tesis doctorales, capacitaciónes para acceder a una cátedra de universidad & prospectos.
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Editorial Cuvillier

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Enantiopure Iminophosphonamide Complexes: Synthesis, Photoluminescence and Catalysis

Impresion
EUR 62,90

E-Book
EUR 44,90

Enantiopure Iminophosphonamide Complexes: Synthesis, Photoluminescence and Catalysis (Tienda española)

Bhupendra Goswami (Autor)

Previo

Lectura de prueba, PDF (370 KB)
Indice, PDF (110 KB)

ISBN-13 (Impresion) 9783736973275
ISBN-13 (E-Book) 9783736963276
Idioma Inglés
Numero de paginas 222
Laminacion de la cubierta mate
Edicion 1
Lugar de publicacion Göttingen
Lugar de la disertacion Karlsruhe
Fecha de publicacion 02.12.2020
Clasificacion simple Tesis doctoral
Area Química inorgánica
Descripcion

The thesis presents about the synthesis of enantiopure iminophosphonamide (NPN) complexes, and their study in catalysis and photoluminescence. The thesis is presented in chapters which is further divided into sections. Initial sections start with the general introduction about the iminophosphonamide ligand system and the corresponding coordination chemistry along with the general hydroboration and photoluminescence. The commonly used iminophosphonamide in coordination chemistry are achiral analogue in contrast to their chiral congeners. The next section of the thesis deals with the synthesis and characterisation of the novel chiral iminophosphonamine ligands and further reactivity with various metals such as the s block metals, d10 configured (i.e. Cu(I) and Zn(II)) metals, group 13 metals, group 4 metals, lanthanide and low valent group 14 compounds. The synthesised s block metal complexes showed interesting photoluminescence with thermally activated delayed fluorescence (TADF) and homoleptic calcium complexes of the substituted iminophosphonamide catalysed the hydroboration of ketones into corresponding alkoxyboronate ester.