Editorial Cuvillier

Publicaciones, tesis doctorales, capacitaciónes para acceder a una cátedra de universidad & prospectos.
Su editorial internacional especializado en ciencias y economia

Editorial Cuvillier

De En Es
Experimental and model-based investigation of overpotentials during oxygen reduction reaction in silver-based gas-diffusion electrodes

EUR 45,48

EUR 32,28

Experimental and model-based investigation of overpotentials during oxygen reduction reaction in silver-based gas-diffusion electrodes (Tienda española)

David Franzen (Autor)


Lectura de prueba, PDF (180 KB)
Indice, PDF (72 KB)

ISBN-13 (Impresion) 9783736975149
ISBN-13 (E-Book) 9783736965140
Idioma Inglés
Numero de paginas 136
Laminacion de la cubierta mate
Edicion 1.
Lugar de publicacion Göttingen
Lugar de la disertacion Clausthal-Zellerfeld
Fecha de publicacion 26.10.2021
Clasificacion simple Tesis doctoral
Area Química industrial e Ingeniería química
Ingeniería mecánica y de proceso
Allgemeine Verfahrenstechnik
Palabras claves gas-diffusion electrode, oxygen reduction reaction, graded electrode, modelling, electrolyte distribution, chlor-alkali electrolysis, oxygen depolarized cathode, silver, operando measurements, diffusion, electrochemistry, experimental studies, transport mechanics, Gasdiffusionselektrode, Sauerstoffreduktion, gradierte Elektrode, Modellierung, Modell, Elektrolytverteilung, Chlor-Alkali-Elektrolyse, Sauerstoffverzehrkathode, Silber, Operando-Messungen, Diffusion, Elektrochemie, experimentelle Untersuchungen, Transportmechanismen, energieintensive Elektrolyseverfahren, energy intensive electrolysis processes, electrical energy, Chlorproduktion, Sauerstoffverzehrkathoden, oxygen depolarized cathodes, Wasserstoffentwicklung, hydrogen evolution, Sauerstoffreduktion, oxygen reduction, Gasdiffusionselektrode, gas-diffusion electrode, Synchrotronstrahlung, synchrotron radiation, Elektrodenleistung, electrodes performance, Radiographien, radiographs, Hydroxidionen, hydroxide ions, Elektrochemische Operando-Messung,Operando-Elektrolyt-Verteilung, Operando electrolyte distribution, Polarisationskurve, polarization curve, Elektrolyt-Eindringtiefe, electrolyte intrusion depth, Kapillarflussporometrie, Elektrolyteigenschaften, electrolyte properties, Agglomeratradius, agglomerate radius, Stromdichte, Elektrolytmasse, electrolyte bulk, Gasraum, gas compartment, Umkehrpunkt, reversal point, Intrusionstiefe, intrusion depth, Porennetzwerk, pore network, Elektrolytsättigung, electrolyte saturation, electrowetting, Elektrobenetzung, Brennstoffzellenelektroden, fuel cells electrodes, elektrochemische Reduktion von CO2, electrochemical reduction of CO2
URL para pagina web externa https://www.icvt.tu-clausthal.de/

Chlorine is one of the most important basic chemicals, which is used directly or indirectly in the production of around 60 % of all chemical products. The production is almost exclusively based on energy intensive electrolysis processes, with an average of 2.5 – 3.5 MWh of electrical energy required per ton of chlorine generated. This means that chlorine production alone accounts for around 3 % of the electrical energy used worldwide in industry. By using oxygen depolarized cathodes (ODC), it is possible to reduce the demand for electrical energy on an industrial scale by about 25 %. Instead of hydrogen evolution, oxygen reduction takes place. Due to the low solubility of oxygen, the electrode is designed as a gas-diffusion electrodes (GDE). These are porous silver-based electrodes with hydrophobic regions due to the use of polytetrafluoroethylene (PTFE). During operation, the liquid electrolyte penetrates the pore structure, but the PTFE prevents complete flooding of the electrode. Oxygen is supplied via a gas compartment and enters the internal structure of the electrode. A three-phase interface is formed, consisting of liquid electrolyte, gas and catalytically active solid, at which the electrochemical reaction takes place. Although the technology is already successfully used industrially, many processes, especially the electrolyte distribution, inside the GDE remain unknown.
In this dissertation, the influence of PTFE is first systematically investigated. Subsequently the process is described in a pseudo-2D model supported by operando experiments. Finally, the exact penetration depth of the electrolyte is analyzed using specially designed electrodes.