Synthesis of Heterometallic Zinc-Gold and Lanthanide-Transition Metal Carbonyl Complexes and Reactivity Study of Pentaphosphaferrocene Towards Low-Valent Main Group Species

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Leseprobe, PDF (820 KB)
Inhaltsverzeichnis, PDF (590 KB)

The work reported in this thesis is divided into three parts.
In the first part, the synthesis of Zn-Au heterometallic complexes is described by using bifunctional carboxy-phosphine ligands.
The second part of this thesis focuses on redox reactions between divalent lanthanides (LnII) and transition metal™ carbonyl complexes for the synthesis of high nuclearity heterometallic complexes.
The third and final part of this thesis focuses on reactivity studies of [Cp*Fe(Л5-P5)] with lowvalent main group compounds.