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Lowering of the boiling curve of biodiesel by metathesis

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Lowering of the boiling curve of biodiesel by metathesis (Volumen 4)

Jürgen Bünger (Editor)
Peter Eilts (Editor)
Axel Munack (Editor)
Jürgen Krahl (Editor)

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Lectura de prueba, PDF (230 KB)
Indice, PDF (84 KB)

ISBN-13 (Impresion) 9783954045549
ISBN-13 (E-Book) 9783736945548
Idioma Inglés
Numero de paginas 98
Laminacion de la cubierta Brillante
Edicion 1. Aufl.
Serie Fuels Joint Research Group - Interdisziplinäre Kraftstoffforschung für die Mobilität der Zukunft
Volumen 4
Lugar de publicacion Göttingen
Fecha de publicacion 21.01.2014
Clasificacion simple Libro de divulgacion
Area Química
Ingeniería mecánica y de proceso
Palabras claves diesel fuel, biodiesel, metathesis, metathesis fuel, boiling curve, boiling line, diesel engines, diesel, engine oil, exhaust emissions, health effects, polycyclic aromatic hydrocarbons, PAH, Organische Chemie, Strömungs- und Kolbenmaschinen
Descripcion

The boiling line of diesel fuels is relevant for the combustion in modern engines. Biodiesel shows a boiling behavior that is very different to diesel fuel. To adapt the boiling line, metathesis reactions were carried out. Different products were obtained by varying the catalysts and the ratio of biodiesel to 1-hexene. As 20%-blends in diesel fuel some metathesis products were quite similar to the diesel fuel boiling line. The metathesis fuels were tested regarding interactions with other fuel components and engine oil. Additionally, the material compatibility was in focus. Corrosion effects on copper were within the specification for diesel fuel. Exhaust gas emissions from 20%-blends as well as mutagenicity showed no significant deviations versus diesel fuel.

In the result, no significant disadvantages for metathesis fuels were found. However, there production occurs currently only in lab-scale.