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Editorial Cuvillier

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Novel N-Heterocyclic Carbene Ligands and their Metal Complexes

Impresion
EUR 41,25

E-Book
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Novel N-Heterocyclic Carbene Ligands and their Metal Complexes (Tienda española)

Tongxun Guo (Autor)

Previo

Indice, PDF (99 KB)
Lectura de prueba, PDF (460 KB)

ISBN-13 (Impresion) 9783954049998
ISBN-13 (E-Book) 9783736949997
Idioma Inglés
Numero de paginas 198
Laminacion de la cubierta mate
Edicion 1. Aufl.
Lugar de publicacion Göttingen
Lugar de la disertacion Göttingen
Fecha de publicacion 21.05.2015
Clasificacion simple Tesis doctoral
Area Química
Palabras claves N-heterocyclic carbene, metal complex, novel carbene, DFT calculation, X-ray diffraction
Descripcion

N-heterocyclic carbenes (NHCs) have found robust development and were widely used as ubiquitous ligands for organometallic complexes in the past two decades. Besides the most popular Arduengo carbenes, i.e. imidazol-2-ylidene and its analogues, novel carbenes derived from N-heterocycles other than imidazole have lately attracted increasing attention. In this work, metal complexes with novel N-heterocyclic carbene ligands, such as imidazol-4/5-ylidene, pyridazin-4-ylidene, and N-metallated N-heterocyclic carbene have been synthesized and characterized. In addition, inspired by a recent discovery that a carbon atom was chelated by NHC ligands to form carbodicarbene, efforts to synthesize a novel indene-derived carbene, in which NHC ligands coordinate to carbon atoms adjacent to the carbenic carbon atom, have been carried out.