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Novel N-Heterocyclic Carbene Ligands and their Metal Complexes

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Novel N-Heterocyclic Carbene Ligands and their Metal Complexes (English shop)

Tongxun Guo (Author)

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ISBN-13 (Hard Copy) 9783954049998
ISBN-13 (eBook) 9783736949997
Language English
Page Number 198
Lamination of Cover matt
Edition 1. Aufl.
Publication Place Göttingen
Place of Dissertation Göttingen
Publication Date 2015-05-21
General Categorization Dissertation
Departments Chemistry
Keywords N-heterocyclic carbene, metal complex, novel carbene, DFT calculation, X-ray diffraction
Description

N-heterocyclic carbenes (NHCs) have found robust development and were widely used as ubiquitous ligands for organometallic complexes in the past two decades. Besides the most popular Arduengo carbenes, i.e. imidazol-2-ylidene and its analogues, novel carbenes derived from N-heterocycles other than imidazole have lately attracted increasing attention. In this work, metal complexes with novel N-heterocyclic carbene ligands, such as imidazol-4/5-ylidene, pyridazin-4-ylidene, and N-metallated N-heterocyclic carbene have been synthesized and characterized. In addition, inspired by a recent discovery that a carbon atom was chelated by NHC ligands to form carbodicarbene, efforts to synthesize a novel indene-derived carbene, in which NHC ligands coordinate to carbon atoms adjacent to the carbenic carbon atom, have been carried out.