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Leitlinien Unfallchirurgie
5. Auflage bestellen |
Table of Contents, PDF (99 KB)
Extract, PDF (460 KB)
ISBN-13 (Hard Copy) | 9783954049998 |
ISBN-13 (eBook) | 9783736949997 |
Language | English |
Page Number | 198 |
Lamination of Cover | matt |
Edition | 1. Aufl. |
Publication Place | Göttingen |
Place of Dissertation | Göttingen |
Publication Date | 2015-05-21 |
General Categorization | Dissertation |
Departments |
Chemistry
|
Keywords | N-heterocyclic carbene, metal complex, novel carbene, DFT calculation, X-ray diffraction |
N-heterocyclic carbenes (NHCs) have found robust development and were widely used as ubiquitous ligands for organometallic complexes in the past two decades. Besides the most popular Arduengo carbenes, i.e. imidazol-2-ylidene and its analogues, novel carbenes derived from N-heterocycles other than imidazole have lately attracted increasing attention. In this work, metal complexes with novel N-heterocyclic carbene ligands, such as imidazol-4/5-ylidene, pyridazin-4-ylidene, and N-metallated N-heterocyclic carbene have been synthesized and characterized. In addition, inspired by a recent discovery that a carbon atom was chelated by NHC ligands to form carbodicarbene, efforts to synthesize a novel indene-derived carbene, in which NHC ligands coordinate to carbon atoms adjacent to the carbenic carbon atom, have been carried out.