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The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).
ISBN-13 (Impresion) | 9783736970342 |
ISBN-13 (E-Book) | 9783736960343 |
Idioma | Inglés |
Numero de paginas | 138 |
Laminacion de la cubierta | mate |
Edicion | 1. |
Lugar de publicacion | Göttingen |
Fecha de publicacion | 20.06.2019 |
Clasificacion simple | Tesis doctoral |
Area |
Química
|
Palabras claves | Synthesis, Structural Characterization, Arsinoamide, Phosphinoamide, Metal complexes, Nitrogen, titanium, heterobimetallic, crystallographically, metal-to-metal, suitable ligands, boron, aluminum, gallium, indium, thallium, intermolecular, magnetic resonance, |