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Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes

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EUR 38,64

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EUR 27,05

Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes (Tienda española)

Chen Xiao (Autor)

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The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).

ISBN-13 (Impresion) 9783736970342
ISBN-13 (E-Book) 9783736960343
Idioma Inglés
Numero de paginas 138
Laminacion de la cubierta mate
Edicion 1.
Lugar de publicacion Göttingen
Fecha de publicacion 20.06.2019
Clasificacion simple Tesis doctoral
Area Química
Palabras claves Synthesis, Structural Characterization, Arsinoamide, Phosphinoamide, Metal complexes, Nitrogen, titanium, heterobimetallic, crystallographically, metal-to-metal, suitable ligands, boron, aluminum, gallium, indium, thallium, intermolecular, magnetic resonance,