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Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes (Tienda española)
Chen Xiao (Autor)Previo
Indice, PDF (140 KB)
Lectura de prueba, PDF (500 KB)
| ISBN-13 (Impresion) | 9783736970342 |
| ISBN-13 (E-Book) | 9783736960343 |
| Idioma | Inglés |
| Numero de paginas | 138 |
| Laminacion de la cubierta | mate |
| Edicion | 1. |
| Lugar de publicacion | Göttingen |
| Fecha de publicacion | 20.06.2019 |
| Clasificacion simple | Tesis doctoral |
| Area |
Química
|
| Palabras claves | Synthesis, Structural Characterization, Arsinoamide, Phosphinoamide, Metal complexes, Nitrogen, titanium, heterobimetallic, crystallographically, metal-to-metal, suitable ligands, boron, aluminum, gallium, indium, thallium, intermolecular, magnetic resonance, |
Descripcion
The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).
