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Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes

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Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes (English shop)

Chen Xiao (Author)

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ISBN-13 (Hard Copy) 9783736970342
ISBN-13 (eBook) 9783736960343
Language English
Page Number 138
Lamination of Cover matt
Edition 1.
Publication Place Göttingen
Publication Date 2019-06-20
General Categorization Dissertation
Departments Chemistry
Keywords Synthesis, Structural Characterization, Arsinoamide, Phosphinoamide, Metal complexes, Nitrogen, titanium, heterobimetallic, crystallographically, metal-to-metal, suitable ligands, boron, aluminum, gallium, indium, thallium, intermolecular, magnetic resonance,
Description

The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).