Cuvillier Verlag
| Departments | |
|---|---|
| Book Series (90) |
1259
|
| Humanities |
2245
|
| Natural Sciences |
5309
|
| Mathematics | 223 |
| Informatics | 310 |
| Physics | 971 |
| Chemistry | 1346 |
| Geosciences | 130 |
| Human medicine | 241 |
| Stomatology | 10 |
| Veterinary medicine | 98 |
| Pharmacy | 147 |
| Biology | 812 |
| Biochemistry, molecular biology, gene technology | 114 |
| Biophysics | 25 |
| Domestic and nutritional science | 44 |
| Agricultural science | 992 |
| Forest science | 202 |
| Horticultural science | 18 |
| Environmental research, ecology and landscape conservation | 145 |
| Engineering |
1712
|
| Common |
91
|
|
Leitlinien Unfallchirurgie
5. Auflage bestellen |
|
Advanced Search
Hard Copy
EUR 38.64
E-book
EUR 27.05
Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes (English shop)
Chen Xiao (Author)Preview
Table of Contents, PDF (140 KB)
Extract, PDF (500 KB)
| ISBN-13 (Hard Copy) | 9783736970342 |
| ISBN-13 (eBook) | 9783736960343 |
| Language | English |
| Page Number | 138 |
| Lamination of Cover | matt |
| Edition | 1. |
| Publication Place | Göttingen |
| Publication Date | 2019-06-20 |
| General Categorization | Dissertation |
| Departments |
Chemistry
|
| Keywords | Synthesis, Structural Characterization, Arsinoamide, Phosphinoamide, Metal complexes, Nitrogen, titanium, heterobimetallic, crystallographically, metal-to-metal, suitable ligands, boron, aluminum, gallium, indium, thallium, intermolecular, magnetic resonance, |
Description
The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).
