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Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes

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Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes

Chen Xiao (Autor)

Vorschau

Inhaltsverzeichnis, PDF (140 KB)
Leseprobe, PDF (500 KB)

ISBN-13 (Printausgabe) 9783736970342
ISBN-13 (E-Book) 9783736960343
Sprache Englisch
Seitenanzahl 138
Umschlagkaschierung matt
Auflage 1.
Erscheinungsort Göttingen
Erscheinungsdatum 20.06.2019
Allgemeine Einordnung Dissertation
Fachbereiche Chemie
Schlagwörter Synthesis, Structural Characterization, Arsinoamide, Phosphinoamide, Metal complexes, Nitrogen, titanium, heterobimetallic, crystallographically, metal-to-metal, suitable ligands, boron, aluminum, gallium, indium, thallium, intermolecular, magnetic resonance,
Beschreibung

The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).