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Screening of Chiral Diels-Alder Catalysts by Mass Spectrometric Monitoring of the Retro Reaction (English shop)
Antje Maria Teichert (Author)Preview
Table of Contents, Datei (33 KB)
Extract, Datei (130 KB)
| ISBN-13 (Printausgabe) | 3867274452 |
| ISBN-13 (Hard Copy) | 9783867274456 |
| ISBN-13 (eBook) | 9783736924451 |
| Language | English |
| Page Number | 226 |
| Edition | 1 |
| Volume | 0 |
| Publication Place | Göttingen |
| Place of Dissertation | Basel |
| Publication Date | 2007-12-07 |
| General Categorization | Dissertation |
| Departments |
Chemistry
|
| Keywords | asymmetric catalysis, eletrospray ionisation mass spectrometry, high-troughput screening, homogeneous catalysis, retro-Diels-Alder reaction. |
Description
Rapid catalyst screening for enantioselective Diels-Alder reactions was accomplished by mass spectrometric monitoring of reaction intermediates of the retro-Diels-Alder reaction. Copper catalysts as well as metal-free organocatalysts were tested. Furthermore, a protocol for simultaneous screening of catalyst mixtures was developed, offering new possibilities for high-throughput catalyst development.
