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Coumarin-based Coinage Metal Complexes: Synthesis, Luminescence and Cytotoxicity Studies

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Coumarin-based Coinage Metal Complexes: Synthesis, Luminescence and Cytotoxicity Studies (English shop)

Vanitha Reddy Naina (Author)


Extract, PDF (810 KB)
Table of Contents, PDF (98 KB)

ISBN-13 (Hard Copy) 9783736978904
ISBN-13 (eBook) 9783736968905
Language English
Page Number 168
Lamination of Cover matt
Edition 1.
Publication Place Göttingen
Place of Dissertation Karlsruher Instituts für Technologie
Publication Date 2023-10-04
General Categorization Dissertation
Departments Chemistry
Keywords CAAC, cyclic amino alkyl carbene, OLED, organic light emmiting diode, zyklische Amino-Alkylcarben, organische Leuchtdiode, potassium graphite, Kaliumgraphit, photluminescence excitation, Photolumineszenz-Anregung, picosecond, Pikosekunde, HRESI-MS high resolution electron spray, Hochauflösendes HRESI-MS-Elektronenspray, Ionisationsmassenspektrometrie, ionization mass spectrometry, chemische Verschiebung, chemical shift

The dissertation focuses on using 7-amino-4-methylcoumarin as a photophysically active group in designing hybrid ligands and their metal complexes.
Further, the functionalization of the amino group was carried out only at the 7-position to synthesize ligands and coinage metalccomplexes.
The coinage metals were chosen mainly due to their d10 electronic configuration since fully filled d-orbitals were known to exhibit interesting optical properties.
The synthesized metal complexes were characterized using standard analytical tools and investigated for their photophysical properties.
Further, the experimental findings are supported by quantum chemical calculations.