Cookies help us deliver our services. By using our services, you agree to our use of cookies.
De En Es
Kundenservice: +49 (0) 551 - 547 24 0

Cuvillier Verlag

Publications, Dissertations, Habilitations & Brochures.
International Specialist Publishing House for Science and Economy

Cuvillier Verlag

Premiumpartner
De En Es
Titelbild-leitlinien
Identification of electrochemical reaction kinetics by dynamic methods

Hard Copy
EUR 49.90

Identification of electrochemical reaction kinetics by dynamic methods

Fabian Kubannek (Author)

Preview

Table of Contents, PDF (53 KB)
Extract, PDF (200 KB)

ISBN-13 (Hard Copy) 9783736970540
Language English
Page Number 200
Edition 1.
Publication Place Göttingen
Place of Dissertation Braunschweig
Publication Date 2019-07-30
General Categorization Dissertation
Departments Chemistry
Industrial chemistry and chemical engineering
Mechanical and process engineering
Keywords Acetate oxidation, Bioelectrochemical system, Chemical Engineering, Catalyst, CO oxidation, Concentration pulse method, Cyclic voltammetry, Differential electrochemical mass spectrometry, Dynamic methods, Electrochemical impedance spectroscopy, Electrochemistry, Energy conversion, Frequency response analysis, Geobacter sulfurreducens, Glycerol oxidation, Heterogeneous catalysis, High pressure liquid chromatography, In-situ techniques, Macrokinetics, Mass transfer, Methanol oxidation, Microbial fuel cell, Modelling, Non-turnover-CV, Parameter identification, Platinum, Quantitative analysis, Reaction kinetics, Ruthenium, Simulation, Technical electrode, Turnover-CV
URL to External Homepage https://www.tu-braunschweig.de/ines
Description

Electrochemical energy conversion technologies are often seen as key components for the transition to an economy that is powered by renewable energy sources. Knowledge-based design and systematic improvement of electrochemical processes is only possible if the underlying reaction kinetics are well understood.
This work is based on the hypothesis that a combination of dynamic electrochemical methods, in-operando techniques, and simulations is a feasible and advantageous way towards the determination of electrochemical reaction kinetics. To demonstrate advantages of such a combined approach, four model systems are studied. Differential electrochemical mass spectrometry (DEMS) data and electrochemical data is used to parameterise physical models of the CO and methanol electrooxidation. The second part covers bioelectrochemical reactions. The first DEMS results on acetate oxidation in electrochemically active biofilms are presented, and storage mechanisms for charge as well as substrate are quantified. Furthermore, conversion pathways and rate constants in bioelectrochemical glycerol oxidation are investigated. In conclusion, it is demonstrated that the identification of electrochemical macrokinetics benefits significantly from the application of dynamic techniques, concentration measurements, physical simulation models.